Activated Carbon Preparation and Modification for Adsorption

Butanol is considered a promising, infrastructure-compatible biofuel. Butanol has a higher energy content than ethanol and can be used in conventional gas engines without modifications. Unfortunately, the fermentation pathway for butanol production is restricted by its toxicity to the microbial strains used in the process. Butanol is toxic to the microbes, and this can slow fermentation rates and reduce butanol yields. Gas stripping technology can efficiently remove butanol from the fermentation broth as it is produced, thereby decreasing its inhibitory effects. Traditional butanol separation heavily depends on the energy intensive distillation method. One of the main issues in acetone-butanol-ethanol fermentation is that butanol concentrations in the fermentation broth are low, ranging from 1 to 1.2 percent in weight, because of its toxicity to the microorganisms. Therefore distillation of butanol is even worse than distillation of corn ethanol. Even new separation methods, such as solidextraction methods involve adding substances, such as polymer resin and zeolite or activated carbon, to biobutanol fermentatioon broth did not achieve energy efficient separation of butanol due to low adsorption selectivity and fouling in broth. Gas-stripping - condensation is another new butanol recovery method, however, the butanol in gasstripping stream is too low to be condensed without using expensive and energy intensive liquid nitrogen. Adsorption can then be used to recover butanol from the vapor phase. Activated carbon (AC) samples and zeolite were investigated for their butanol vapor adsorption capacities. Commercial activated carbon was modified via hydrothermalH2O2treatment, and the specific surface area and oxygen-containing functional groups of activated carbon were tested before and after treatment. Hydrothermal H2O2 modification increased the surface oxygen content, Brunauer-Emmett-Teller surface area, micropore volume, and total pore volume of active carbon. The adsorption capacities of these active carbon samples were almost three times that of zeolite. However, the un-modified active carbon had the highest adsorption capacity for butanol vapor (259.6 mg g-1), compared to 222.4 mg g-1 after 10% H2O2 hydrothermal treatment. Both modified and un-modified active carbon can be easily regenerated for repeatable adsorption by heating to 150. Therefore, surface oxygen groups significantly reduced the adsorption capacity of active carbons for butanol vapor. In addition, original active carbon and AC samples modified by nitric acid hydrothermal modification were assessed for their ability to adsorb butanol vapor. The specific surface area and oxygen-containing functional groups of AC were tested before and after modification. The adsorption capacity of unmodified AC samples were the highest. Hydrothermal oxidation of AC with HNO3 increased the surface oxygen content, Brunauer-Emmett-Teller (BET) surface area, micropore, mesopore and total pore volume of AC. Although the pore structure and specific surface area were greatly improved after hydrothermal oxidization with 4 M HNO3, the increased oxygen on the surface of AC decreased the dynamic adsorption capacity. In order to get high adsorption capacity adsorbents, we used corn stalk as precursor to fabricate porous carbon. ACs were prepared through chemical activation of biochar from whole corn stalk (WCS) and corn stalk pith (CSP) at varying temperatures using potassium hydroxide as the activating agent. ACs were characterized via pore structural analysis and scanning electron microscopy (SEM). These adsorbents were then assessed for their adsorption capacity for butanol vapor. It was found that WCS activated at 900 °C for 1 h (WCS-900) had optimal butanol adsorption characteristics. The BET surface area and total pore volume of the WCS-900 were 2330 m2 g-1 and 1.29 cm3 g-1, respectively. The dynamic adsorption capacity of butanol vapor was 410.0 mg g-1, a 185.1 % increase compared to charcoal-based commercial AC (143.8 mg g-1). Based on the adsorption experiments of butanol vapor, we found the chemical properties of the AC surface play an important role in adsorbing molecules. The adsorption of creatinine on active carbons was also studied, which is a toxic compound generated by human. High levels of creatinine in the blood stream is normally caused by malfunction or failure of the kidneys. Activated carbons is taken by the patients orally to reduce creatinine level. In order to figure out whether chemical modification could increase the adsorption capacity of creatinine, AC samples modified by nitric acid hydrothermal modification were assessed for their ability to adsorb creatinine. The pore structure and surface properties of the AC samples were characterized by N2 adsorption, temperature programmed desorption (TPD), Fourier Transform Infrared spectroscopy (FTIR), and Xray photoelectron spectrometer (XPS). It indicated that 4M HNO3 hydrothermal modification with 180 °C was an efficient method in improvement of the creatinine adsorption. The improved adsorption capacity can be attributed mainly to an increase in the acidic oxygen-containing functional groups. The adsorption of creatinine over AC may involve an interaction with the acidic oxygen-containing groups on AC. Langmuir and Freundlich adsorption models were applied to describe the experimental isotherm and isotherm constants. Equilibrium data fitted very well to the Freundlich model in the entire saturation range (3.58-59.08 mg L-1). The maximum adsorption capacities of AC modified with 180 °C is 62.5 mg g-1 according to the Langmuir model. Pseudo first-order and second-order kinetic models were used to describe the kinetic data and the rate constants were evaluated. The experimental data fitted well to the second-order kinetic model, which indicates that the chemical adsorption was the rate-limiting step, instead of mass transfer

Doherty techniques for 5G RF and mm-wave Power Amplifiers

© 2016 IEEE. 5G poses severe challenges to PA design. In the first place, output power and efficiency are of prime importance because of battery lifetime. The tradeoff between linear output power and efficiency is typically challenged by the high PAPR due to QAM modulation and/or OFDM techniques. But this important trade-off is challenged even more in 5G due to the high bandwidth requirements. Furthermore, the shift to higher frequencies, where more unused spectrum is available, also puts a burden on the overall PA architecture.status: publishe

Exosome: A Novel Nanocarrier Delivering Noncoding RNA for Bone Tissue Engineering

Bone growth and metabolism are mainly regulated by a series of intracellular molecules and extracellular stimuli. Exosome, as a nanoscale substance secreted to the outside of the cells, plays an extensive role in intercellular communication. This review provides theoretical references and evidences for further exploration of exosomes as noncoding RNA carriers to regulate bone tissue recovery through the following aspects: (1) basic characteristics of exosomes, (2) research progress of exosomal noncoding RNA in bone tissue engineering, (3) current status and advantages of engineering exosomes as nanocarriers for noncoding RNA delivery, and (4) problems and application prospects of exosome therapy in the field of orthopedics

Tax Burden and Corporate Investment Efficiency

Using A-share listed companies in Shanghai and Shenzhen from 2015 to 2021 as the research sample, a fixed-effects model was used to examine the effect of the reduction of corporate tax burden on investment efficiency under the tax reduction policy, as well as the role of tax avoidance and financing constraints in the mechanism. The results of the study show that the reduction of tax burden can effectively improve the efficiency of corporate investment, and this positive effect is reflected in the alleviation of corporate under-investment and discouragement of over-investment. The paper also analyses the mechanism through which tax burden affects the efficiency of corporate investment, and finds that tax reduction can discourage inefficient investment by reducing corporate tax avoidance and alleviating corporate financing constraints. In further analysis, it is found that the effect of tax cuts on investment efficiency is more significant in the sample of non-state enterprises, low corporate governance and low marketisation. The findings of the study support the positive significance of the current tax reduction policy. We provide a reference of tax reduction benefits to curb tax avoidance behavior, and provide a basis for relevant policy departments to further accelerate the implementation of tax reduction policies

Tax Burden and Corporate Investment Efficiency

Using A-share listed companies in Shanghai and Shenzhen from 2015 to 2021 as the research sample, a fixed-effects model was used to examine the effect of the reduction of corporate tax burden on investment efficiency under the tax reduction policy, as well as the role of tax avoidance and financing constraints in the mechanism. The results of the study show that the reduction of tax burden can effectively improve the efficiency of corporate investment, and this positive effect is reflected in the alleviation of corporate under-investment and discouragement of over-investment. The paper also analyses the mechanism through which tax burden affects the efficiency of corporate investment, and finds that tax reduction can discourage inefficient investment by reducing corporate tax avoidance and alleviating corporate financing constraints. In further analysis, it is found that the effect of tax cuts on investment efficiency is more significant in the sample of non-state enterprises, low corporate governance and low marketisation. The findings of the study support the positive significance of the current tax reduction policy. We provide a reference of tax reduction benefits to curb tax avoidance behavior, and provide a basis for relevant policy departments to further accelerate the implementation of tax reduction policies

Risk Assessment and Analysis of Rock Burst under High-Temperature Liquid Nitrogen Cooling

Rock burst, an important kind of geological disaster, often occurs in underground construction. Rock burst risk assessment, as an important part of engineering risk assessment, cannot be ignored. Liquid nitrogen fracturing is a new technology used in the geological, oil, and gas industries to enhance productivity. It involves injecting liquid nitrogen into reservoir rocks to induce fractures and increase permeability, effectively reducing rock burst occurrences and facilitating the flow of oil or gas toward the wellbore. The research on rock burst risk assessment technology is the basis of reducing rock burst geological disasters, which has important theoretical and practical significance. This article examines the temperature treatment of two types of rocks at 25 °C, 100 °C, 200 °C, 300 °C, and 400 °C, followed by immersion in a liquid nitrogen tank. The temperature difference between the liquid nitrogen and the rocks may trigger rock bursting. The research focused on analyzing various characteristics of rock samples when exposed to liquid nitrogen. This included studying the stress–strain curve, elastic modulus, strength, cross-section analysis, wave velocity, and other relevant aspects. Under the influence of high temperature and a liquid nitrogen jet, the wave velocity of rocks often changes. The structural characteristics and possible hidden dangers of rocks can be understood more comprehensively through section scanning analysis. The stress–strain curve describes the deformation and failure behavior of rocks under different stress levels, which can help to evaluate their stability and structural performance. The investigation specifically focused on the behavior of rocks subjected to high temperatures and liquid nitrogen. By analyzing the stress–strain curves, researchers were able to identify the precursors and deformation processes that occur before significant deformation or failure. These findings have implications for the mechanical properties and stability of the rocks

Advances in hexitol and ethylene glycol production by one-pot hydrolytic hydrogenation and hydrogenolysis of cellulose

In this review, recent advances in the one-pot hydrolytic hydrogenation and hydrogenolysis of cellulose to value-added polyols, including hexitols (sorbitol, mannitol, and isosorbide) and 1,2-alkanediols (ethylene glycol and 1,2-propylene glycol), are summarized. Methods for the generation of H+ in the first step of cellulose hydrolysis to form intermediate sugars, such as the use of soluble acids (mineral acids and heteropoly acids) and H+ produced in situ from functional supports and H-2 dissociation, are classified and analyzed, considering its combination with active metals for the subsequent hydrogenation or hydrogenolysis of sugars to polyols. The interaction of non-noble metals such as nickel, bimetals, and tungsten with support materials in the catalytic conversion of intermediate sugars to hexitols and ethylene glycol is reviewed. The corresponding reaction pathways and mechanisms are discussed, including the conversion process using basic supports and solution conditions. Major challenges and promising routes are also suggested for the future development of the chemocatalytic conversion of cellulose. (C) 2015 Elsevier Ltd. All rights reserved